Safety Data Sheet
NOTE: Access to a copy of this Safety Data Sheet (SDS) via our Website does not constitute the issue of a controlled Copy under EU legislation. To be issued with such a copy please contact Rentokil Initial at the address below by telephone, fax or in writing. In order to confirm the latest version of the SDS for this product see wnd click on Technical Information / Product Safety.
17 : 10 : 2007 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY RENTOKIL INSECTROL PROFESSIONAL Product Name Description
A hand-held, insecticidal aerosol spray with a kerosene type odour. For professional use against cockroaches, fleas, ants, beetles, earwigs, bedbugs, woodlice and other insects.
Rentokil Initial Supplies, Liverpool, L33 7SR. Product advice line: 0151 548 5050 Emergency line: 01342 833022 E-mail: [email protected]IDENTIFICATION Classification (Supply – Use) : In compliance with EC Directive 1999/45. F+ Extremely Flammable R12 Dangerous for the
R50/53 Very toxic to aquatic organisms, may cause long-term
Environment
adverse effects in the aquatic environment.
Harmful: may cause lung damage if swallowed.
Adverse Physical, Chemical, Significant Human Health and Environmental Effects (See also box 11): Product is extremely flammable, do not use near sources of ignition (e.g. naked flames).
Direct contact with the aerosol spray may cause cold burns to the eyes and skin. Inhalation of the spray may cause irritation of the nose, throat and respiratory tract. Inhalation of high vapour concentrations may result in drowsiness, nausea, dizziness and ultimately loss of consciousness. Ingestion may cause irritation of the throat, nausea and vomiting. Ingestion of large quantities may lead to neurological symptoms such as ataxia and tremors, nausea, vomiting and loss of consciousness. Inhalation of the vapour whilst swallowing or vomiting may cause lung damage. Intentional misuse by deliberately concentrating or inhaling the contents can be harmful or fatal.
COMPOSITION / INFORMATION ON INGREDIENTS (SEE ALSO BOX 16) Common*/Chemical Name, ELINCS/EINECS & CAS No. of Ingredients EC 1999/45 Classification
Permethrin* / 3-phenoxybenzyl (1RS, 3RS ; 1RS, 3RS)-3-(2,2-dichlorovinyl)-2,2-
d-Allethrin* / (RS)-3-allyl-2-methyl-4-oxocyclopent-2-enyl (1R)-cis-trans-
chrysanthemate 2-methyl-4-oxo-3-(2-propenyl)-2-cyclopenten-1-yl 2,2-dimethyl-3-
(2-methyl-1-propenyl)cyclopropanecarboxylate
≤100.0 Aliphatic hydrocarbon* / naphtha (petroleum)
≤50.0 Aerosol propellant* / liquefied petroleum gas
RENTOKIL INSECTROL PROFESSIONAL INSECT KILLER SDS No. 928 Issue: 01 17 : 10 : 2007 Page 1 of 4 FIRST-AID MEASURES (SEE ALSO “ADVERSE EFFECTS” IN BOX 2) Inhalation
Remove patient to fresh air, keep warm and at rest. Apply supportive measures if necessary and seek medical attention.
Eye Contact
Rinse affected eye with clean running water, or eyewash solution, for at least 15 minutes holding eyelids well apart. Rinse entire surface and do not allow run-off to contaminate unaffected eye. Seek medical attention.
Skin Contact
Remove and wash contaminated clothing immediately. Wash affected area thoroughly with soap and water. If the patient feels unwell seek medical advice.
Ingestion
Do NOT induce vomiting. If unconscious place in the recovery position and apply supportive measures if
(Swallowing)
necessary. If conscious give patient up to ½ litre or 1 pint of water to drink. Seek medical attention.
Emergency
Appropriate first-aid equipment should be provided. For the UK this should be in accordance with the Health &
Equipment Suggested Safety (First-Aid) Regulations 1981. See also the Approved Code of Practice “First-aid at Work”. Note To Doctor
Further information on all Rentokil Initial formulations is lodged with the National Poisons Information Service in the UK.
FIGHTING MEASURES Fire Extinguisher
Use carbon dioxide, foam, or dry powder extinguishers.
Special Fire-Fighting
Wear suitable personal protective equipment.
Procedures Special Exposure
Polycyclic aromatic hydrocarbons, unburnt hydrocarbons, unidentified organic and inorganic compounds
and oxides of nitrogen and carbon may be produced in the event of a fire. Large amounts of propane released in a fire may act as an asphyxiant.
ACCIDENTAL RELEASE MEASURES Personal Precautions Wear suitable personal protective equipment. Remove all sources of ignition. Ensure area is well (See also box 8) Environmental
This product is classified as dangerous for the environment. Keep away from drains, surface and ground
Precautions Clean-up Procedure
If the aerosol container is damaged or pierced, allow the propellant to vent-off, if possible in a well-ventilated
(See also box 13)
area, then place in a suitable container for subsequent disposal or recycling.
HANDLING AND STORAGE (SEE ALSO BOX 8) Handling
Store in original container in a cool, dry, ventilated place out of the reach of children and away from food, drink and animal feeding stuffs. Pressurised container: Protect from sunlight and do not expose to temperatures exceeding 50°C. Keep away from sources of ignition - No smoking.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Standard -
Workplace Exposure Limit (WEL) for aerosol propellant is 1750 mg/m3 long-term exposure (8 hour Time
Directive EC/98/24 (1St
Weighted Average) and 2180 mg/m3 short-term exposure (15 minute reference period).
IOELV Directive)
Aerosol propellant is referred to as liquefied petroleum gas in Directive EC/98/24 (1St IOELV Directive).
Engineering Controls Where exposure may occur, engineering controls, rather than the provision of Personal Protective Equipment
(PPE) should be employed. On completion of a risk assessment, the following PPE may be required:
Eye Protection
Label advice indicates none necessary under normal handling and use. However, consider other precautionary requirements.
Hand Protection
Label advice indicates none necessary under normal handling and use. However, consider other precautionary requirements.
Skin Protection
Label advice indicates none necessary under normal handling and use. However, consider other precautionary requirements.
Breathing Protection
Label advice indicates none necessary under normal handling and use. However, consider other precautionary requirements.
Environmental
Use only in accordance with instructions given.
Exposure Controls PHYSICAL AND CHEMICAL PROPERTIES Appearance and Odour An aerosol spray with a kerosene type odour. pH Solubility in Water Solubility in Other Solvents Miscible. Flash Point Explosive Properties
Pressurised container: do not puncture or expose to high temperatures.
Flammability Combustibility Boiling Point/Range Oxidising Properties Vapour Density Evaporation Rate Vapour Pressure Partition Coefficient Viscosity Other Data RENTOKIL INSECTROL PROFESSIONAL INSECT KILLER SDS No. 928 Issue: 01 17 : 10 : 2007 Page 2 of 4 STABILITY AND REACTIVITY Conditions to avoid
Avoid exposure to direct sunlight or temperatures exceeding 50°C. Do not pierce or burn even after use.
Materials to avoid
Do not spray on naked flame, electrical equipment or any incandescent material.
Hazardous Breakdown
Polycyclic aromatic hydrocarbons, unburnt hydrocarbons, unidentified organic and inorganic
Products
compounds and oxides of nitrogen and carbon may be produced in the event of a fire. Large amounts of propane released in a fire may act as an asphyxiant.
11 TOXICOLOGICAL INFORMATION (SEE ALSO BOX 2) Acute Toxicity Oral
For permethrin : LD50 (rat) : 6620 mg/kg For d-allethrin : LD50 (rat) : 1000 mg/kg
Inhalation
For permethrin : LD50 (rat) : > 4.638 mg/L For d-allethrin : LD50 (rat) (2hr) : 2000 mg/m3
For permethrin : LD50 (rat) : >4000 mg/kg For d-allethrin : LD50 (rat) : 2150 mg/kg
Corrosivity/
Direct contact of liquid or cold vapour with the skin may result in cold burns.
Irritation
Direct contact of liquid or cold vapour with the skin may result in corneal damage.
Respiratory
May cause irritation to respiratory tract.
Sensitisation
Contains less than 1% skin sensitisers in the form of permethrin.
Respiratory
Contains no known respiratory sensitisers.
Repeat-Dose Toxicity
Product does not contain any components known to have any effects relating to repeated-dose toxicity.
Mutagenicity
Product does not contain any components known to have a mutagenic effect.
Carcinogenicity
Product does not contain any components known to have a carcinogenic effect.
Reproductive Fertility
Product does not contain any components known to have effects on fertility.
Toxicity Development
Product does not contain any components known to be toxic to the reproductive system.
Other Information 12 ECOLOGICAL INFORMATION General Information
This product is classified as very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. However, when used in accordance with instructions given, controlled release of this product is not expected to cause environmental contamination.
Ecotoxicity Data
LC50 (Oryzias latipes) (48hr) : <1 mg/L
EC50 (Daphnia magna) (48hr) : 0.02 µg/L
EC50 (Daphnia sp) (96hr) : 35.6 µg/L
LC50 (Japanese quails) : >11.275 g/kg
EbC50 (Scendedesmus subspicatus) (72hr) : 1.1 mg/L
LC50 (Colinus virginianus) (8d) : 5620 mg/kg diet
LC50 (Apis mellifera) (48hr) : 3.4 µg/bee
Mobility
d-Allethrin is expected to be mobile and bind to soil. Aerosol propellant will disperse rapidly in air and rapidly evaporate if released to water or soil.
Persistence and
Permethrin is moderately persistent in aquatic organisms.
Degradability
d-Allethrin will biodegrade by up to 28% after 28 days and is photolytically unstable. Photochemical degradation of aerosol propellant in air will proceed at a moderate rate.
Bioaccumulative Potential
Hydrocarbon solvent has a high potential to bioaccumulate.
Other Adverse Effects 13 DISPOSAL CONSIDERATIONS Disposal of Waste /
This product is for amateur use only and can therefore be disposed of as normal household
Containers
waste. However, if used in a place of work, ensure this product is disposed of as hazardous waste, in accordance with the appropriate regulations.
Classification
Hazard Code: H3A(i) – Highly flammable; H5 – Harmful; H14 - Ecotoxic
(Council Directive 91/689/EC,
Components making the waste hazardous Concentrations
Commission Decision 2000/532/EC Permethrin (amended) Commission Decision 2001/118/EC)) Note for Disposal
For further advice about disposal, in the UK, contact the local office of the Environment Agency (England and Wales) or Scottish Environment Protection Agency. Local rate from anywhere in the UK: +44 (0) 870 850 6506.
RENTOKIL INSECTROL PROFESSIONAL INSECT KILLER SDS No. 928 Issue: 01 17 : 10 : 2007 Page 3 of 4 14 TRANSPORT INFORMATION (INTERNATIONAL UNLESS OTHERWISE INDICATED) Tremcard Reference No. Transport Category UK Hazchem EAC Not applicable, aerosols are not
allowed to be carried in tanks or in bulk.
ADR HIN Not applicable, aerosols are not (International Road)
allowed to be carried in tanks or in bulk.
Proper Shipping Limited Quantity
Individual aerosols should not exceed 1000ml and be carried in combination packages
Exemptions
not exceeding 30kg. If carried in shrink-wrapped trays, the total gross mass of the package must not exceed 20kg.
Special Requirements Not required. Packing Group Not required. IMDG 2006 IMDG EMS F-D, S-U Proper Shipping Limited Quantity
Individual aerosols should not exceed 1000ml and be carried in combination packages
Exemptions
not exceeding 30kg. If carried in shrink-wrapped trays, the total gross mass of the package must not exceed 20kg.
Special Requirements Not required. Packing Group Not required. Note for Transport
Local, State or National requirements may apply to the carriage of this product.
15 REGULATORY INFORMATION (HEALTH AND SAFETY INFORMATION (SEE ALSO BOX 2)) Safety Phrases
S13 : Keep away from food, drink and animal feeding stuffs. S16 : Keep away from sources of ignition – No smoking. S23 : Do not breathe spray. S35 : This material and its container must be disposed of in a safe way. S46 : If swallowed, seek medical advice immediately and show this container or label. S51 : Use only in well-ventilated areas.
Additional Label
Contains permethrin. May produce an allergic reaction.
To avoid risks to man and the environment, comply with the instructions for use.
Legislation
Labelling is in accordance with UK regulations implementing the EC Directive 1999/45. Additional labelling requirements may be necessary in accordance with other National legislation. Outside the UK, the registration of this product may be necessary before use and any additional local requirements must be observed at all times. The information given on this Safety Data Sheet (SDS) does not constitute an assessment in accordance with Control of Substances Hazardous to Health (COSHH) Regulations 2002, in the UK. Other National measures or guidance should be followed where appropriate. Other Information and indication of revisions Packaging Information A 400 mL aerosol can. Revisions Risk phrase text
: Harmful by inhalation and if swallowed.
: May cause sensitisation by skin contact.
: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
: Harmful: May cause lung damage if swallowed.
RENTOKIL INSECTROL PROFESSIONAL INSECT KILLER SDS No. 928 Issue: 01 17: 10 : 2007 Page 4 of 4 Before using any product, ensure that you read and understand its label. The information contained in this safety data sheet is, to the best of our knowledge and belief, accurate and reliable at the time of publication. The information relates only to the specific material designated in this safety data sheet and may not be valid for such material if it is used in combination with any other material(s) or any other use than that specified herein. Rentokil Initial UK Ltd is not liable for the use of this product for any other purpose than that described in this safety data sheet. This does not affect your statutory rights. It is the user’s responsibility to satisfy him/herself as to the suitability in completeness of such information for his/her own particular use.
Copyright (2007) Rentokil Initial plc, European Technical Centre, Felcourt, East Grinstead, West Sussex. RH19 2JY. United Kingdom.
Telephone: +44 (0) 1293 858000 Fax: +44 (0) 1342 836180 Web
¿Cómo utilizar este kit de recursos? Estimado socio: La Agencia Europea para la Seguridad y la Salud en el Trabajo de la UE ha creado este «Kit de recursos» para que participe en la campaña Trabajos saludables sobre evaluación de riesgos, organizando sus propias actividades y eventos. Incluye material en 22 lenguas listo para usar en la campaña y se complementa con el último D
Scientific international publications on Arctic charr from the department of Wildlife, Fish, and Environmental Studies 1989 Eriksson, L.-O. 1989. The present status of Arctic charr rearing in Sweden. EAS Special Nilsson, J. 1989. Selective breeding of Arctic charr ( Salvelinus alpinus ) EAS Special 1990 Linnèr, J., Brännäs, E., Wiklund, B.-S. & Lundqvist, H. 1990. D